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On my lsac account, it says that it will only send out the CAS reports only if a school requests it. Will a school take a couple of days to request my CAS report after I submit my application online?

Or can we send a CAS report at the same time that we submit the application?

The school takes a few days, sometimes even up to a week, to request your CAS report. You pay the $12 per school through LSAC so that it's ready to be sent to the school when requested, but you can't actually send it yourself.