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One of the firms I'm targeting for mass-mail only provides a physical address to send app materials. Obviously, it would be easier for me to e-mail my materials and I think it would be easier for the firm to receive my materials via e-mail. Should I reach out the hiring partners and ask if I can e-mail my materials? Should I just suck it up?

Thanks.

If the firm expressly says "send your application to [physical address]" then just follow the directions. If there's ambiguity you could feel free to ask, but I'm sure the firm is aware that they could give an e-mail address, and they don't.